Flame Atomic Absorption Spectrometry Determination of Trace Amounts of Cadmium and Zinc in Water Samples after Preconcentration onto Modified Amberlite XAD‐4 Resin     

Sayed Zia Mohammadi  Daryoush Afzali  Mohammad Ali Taher  Hedayat Darijani 《洁净——土壤、空气、水》2010,38(2):140-145

In the present article, a procedure for the simultaneous separation and preconcentration of trace amounts of cadmium and zinc is proposed. It is based on the adsorption of cadmium and zinc ions onto a column of Amberlite XAD‐4 resin loaded with aluminon reagent. Cadmium and zinc ions are quantitatively retained on the column in the pH range from 6.5–7.5, at a flow rate of 2 mL min^–1. The cadmium and zinc ions are eluted with 5.0 mL of 5 mol L^–1 HNO₃ solution. Cadmium and zinc are measured by flame atomic absorption spectrometry (FAAS). In the present case, 0.1 μg of cadmium and 0.5 μg of zinc can be concentrated in the column from 1000 mL of aqueous sample, where their concentrations are as low as 0.1 and 0.5 ng mL^–1, respectively. The relative standard deviations, for seven replicated determinations of 1.0 μg mL^–1 of cadmium and zinc, are 1.2 and 1.1%, respectively. The detection limits for cadmium and zinc in the original solution are 0.02 and 0.11 ng mL^–1, respectively. The interference of a large number of anions and cations has been studied and the optimized conditions are utilized for the determination of trace amounts of cadmium and zinc in different environmental and standard samples.  相似文献   

Assessing hydrochemical evolution of groundwater in limestone terrain via principal component analysis   总被引：2，自引：2，他引：0  

Zargham Mohammadi 《Environmental Earth Sciences》2009,59(2):429-439

This paper describes the use of multivariate statistical analysis to trace hydrochemical evolution in a limestone terrain at Zagros region, Iran. The study area includes a deep confined aquifer, overlaid by an unconfined aquifer. The method involves the use of principal component analysis (PCA) to assess and evaluate the hydrochemical evolution based on chemical and isotope variables of 12 piezometers drilled in both the unconfined and confined aquifers. First PCA on all variables shows that water–rock interaction under different conditions with respect to the atmospheric CO₂ is the main process responsible for chemical constituents. As a result, combinations of several ratios such as Ca/TDS, SO₄/TDS and Mg/TDS with physico-chemical and isotope variables reveal different hydrochemical evolution trend in the aquifers. Second PCA on the selective samples and variables reveals that displacement of the unconfined samples from dry to wet season follows a refreshing trend towards river samples that is characterized by reducing electrical conductivity and increasing sulphate and tritium contents. However, the refreshing trend cannot be traced in the confined aquifer samples suggesting no recharge from river to the confined aquifer. Third PCA reveals that, chemical composition of water samples in the unconfined aquifer tends to have considerable difference from each other in the end of recharge period. In contrast, the confined aquifer samples have a tendency to show similar chemical composition during recharge period in comparison to end of dry period. This difference is caused by different mechanism of recharge in the unconfined aquifer (through the whole aquifer surface) and the confined aquifer (through the limited recharge area).  相似文献   

Delineation of groundwater salinization in a coastal aquifer, Bousheher, South of Iran     

Z. Mohammadi  M. Zare  B. Sharifzade 《Environmental Earth Sciences》2012,67(5):1473-1484

The geochemical processes controlling chemical composition of groundwater are studied using hydrochemical and isotopic data in Abdan-Dayer coastal plain, south of Iran. The salinity of groundwater in the coastal plain ranges from 1,000, a fresh end-member, to more than 50,000 μS cm^?1, a saline end-member. Groundwater salinity increases from the recharge area toward areas with a shallow water table close to the Persian Gulf coast due to direct evaporation and sea water intrusion as confirmed by mixing binary diagrams, stable isotope content, and Br^?/Cl^? ratio. Groundwater flow pattern in the study area has been modified due to over-pumping of groundwater in recent years which resulted in further saline water migration toward fresh water and their mixing. The maximum mixing ratio is estimated about 15% in different parts of the study area according to chloride concentration.  相似文献   

DEFLOGIC: a method for assessment of groundwater potential in karst terrains: Gurpi Anticline,southwest Iran     

Zakieh Mohammadi  Farshad Alijani  Kazem Rangzan 《Arabian Journal of Geosciences》2014,7(9):3639-3655

A new hydro-tectonic model, includes eight layers that affect karst hydrogeology was proposed for mapping of groundwater potential in karst areas of Gurpi Anticline, southwest Iran. To produce the groundwater potential map, remote sensing (RS) and GIS techniques were combined with fuzzy logic modeling. Criterion maps include the distances from discharge sites (D), the elevation difference from discharge sites (E), the distance from fractures (F), the fracture length density (L), the slope (O), the lithology (G), the distance from fractures intersections (I), and the fractures intersection density (C) were produced using GIS and RS techniques (DEFLOGIC layers). The approach of fuzzy sets was used to commensurate criterion maps, then fuzzy algebraic sum and gamma operators were applied to aggregate them. The weights of parameters of DEFLOGIC proposed in the range of 1 to 5, which standardized between 0 to 1, based on their importance in karst hydrogeology, professional judgments, and available exploration data. The final groundwater potential maps were verified by geoelectric and well-drilling data. The potential map prepared using fuzzy gamma operator with γ?=?0.92, which it is a flexible distinctive parameters of sum and product of fuzzy operator, depicts the best coincidence with exploration data. The final DEFLOGIC map shows the high groundwater potential in karst formations between Hati and Pebde valleys. The results support the efficiency of DEFLOGIC model to evaluating of groundwater potential in karst terrains, especially in Zagros ranges.  相似文献   

Costs related to drowning and near drowning in northern Iran (Guilan province)     

Ali Davoudi-Kiakalayeh  Koustuv DalalShahrokh Yousefzade-Chabok  Bjarne JanssonReza Mohammadi 《Ocean & Coastal Management》2011,54(3):250-255

In Iran and many other low- and middle-income countries, few studies have been carried out in order to assess which cost analysis methods should be undertaken at the household and community level in relation to incidences of drowning. In this study, we have attempted to develop a model for estimating the impact of the economic burden that drowning and near drowning events incur for victims’ families in the Guilan province in the north of Iran by using an incidence approach. During the financial year of March 2007 to 2008, the following cost-related aspects of drowning episodes were evaluated: (note: main cost elements were income adjusted by family and years) medical costs, productivity loss costs and death costs. A total of 137 drowning fatalities and 104 near drowning incidents were recorded. Males in the age span of 10-29 years constitute a majority of the epidemiology and economy data. When the number of variables included in cost analysis was expanded, the estimated burden of economic duress increased dramatically; however, drowning cost for one drowned victim was equivalent to 17 times the country’s gross domestic product(GDP) per capital. Identification of injured person-based costs in this study will enable development of more effective prevention programs and provide indicators of other costs related to drowning episodes such as property damage and the impact of these accidents on community services and the public health care system.  相似文献   

A late Quaternary lake record from the Qilian Mountains (NW China): evolution of the primary production and the water depth reconstructed from macrofossil, pollen, biomarker, and isotope data   总被引：5，自引：0，他引：5  

Ulrike Herzschuh  Chengjun Zhang  Steffen Mischke  Rainer Herzschuh  Farhid Mohammadi  Birgit Mingram  Harald Kürschner  Frank Riedel 《Global and Planetary Change》2005,46(1-4):361

The history (45–0 ka BP) of the aquatic vegetation composition of the shallow alpine Lake Luanhaizi from the NE Tibetan Plateau is inferred from aquatic plant macrofossil frequencies and aquatic pollen and algae concentrations in the sediments. C/N (range: 0.3–100), δ¹³C (range: −28 to −15‰), and n-alkane measurements yielded further information on the quantitative composition of sedimentary organic matter. The inferred primary production of the former lake ecosystem has been examined in respect of the alternative stable state theory of shallow lakes [Scheffer, M., 1989. Alternative stable states in eutrophic, shallow freshwater systems: a minimal model. Hydrobiological Bulletin 23, 73–83]. Switches between clear and turbid water conditions are explained by a colder climate and forest decline in the catchment area of Lake Luanhaizi. The macrofossil-based reconstruction of past water depth and salinity ranges, as well as other organic matter (OM) proxies allowed climatic inferences of the summer monsoon intensity during the late Quaternary. Around 45 ka BP, conditions similar to or even moister than present-day climate occurred. The Lake Luanhaizi record is further evidence against an extensive glaciation of the Tibetan Plateau and its bordering mountain ranges during the Last Glacial Maximum. Highest lake levels and consequently a strong summer monsoon are recorded for the early Holocene period, while gradually decreasing lake levels are reconstructed for the middle and late Holocene.  相似文献   

Application of number–size (N-S) fractal model for separation of mineralized zones in Dareh-Ashki gold deposit, Muteh Complex, Central Iran     

Alireza Mohammadi  Ahmad Khakzad  Nematolah Rashidnejad Omran  Mohammad Reza Mahvi  Parviz Moarefvand  Peyman Afzal 《Arabian Journal of Geosciences》2013,6(11):4387-4398

The goal of this study is to separate different mineralized zones in Dareh-Ashki gold deposit located in Muteh Complex, Central Iran, by using number–size (N-S) fractal model. The N-S log–log plot shows seven geochemical populations and four Au-mineralized zones. Based on obtained results, Au thresholds are 0.17, 0.32, 6.3, and 12.6 ppm which represent weakly, moderately, highly, and extremely mineralized zones in terms of Au grades, respectively. Au values lower than 0.17 ppm illustrate wall rocks. Main mineralization stage of gold commences from 6.3 ppm in this deposit. The moderately mineralized zone with Au values between 0.32 and 6.3 ppm has occupied the biggest part of the studied deposit. However, highly (with Au values between 6.3 and 12.6 ppm) and extremely (higher than 12.6 ppm) mineralized zones have small extension. Correlation between geological model and results from N-S fractal model reveals that the gold mineralized zones specifically the moderately mineralized zone are situated in green schist units.  相似文献   

Application of weights-of-evidence and certainty factor models and their comparison in landslide susceptibility mapping at Haraz watershed, Iran   总被引：10，自引：1，他引：9  

Hamid Reza Pourghasemi  Biswajeet Pradhan  Candan Gokceoglu  Majid Mohammadi  Hamid Reza Moradi 《Arabian Journal of Geosciences》2013,6(7):2351-2365

The main goal of this study was to investigate the application of the weights-of-evidence and certainty factor approaches for producing landslide susceptibility maps of a landslide-prone area (Haraz) in Iran. For this purpose, the input layers of the landslide conditioning factors were prepared in the first stage. The landslide conditioning factors considered for the study area were slope gradient, slope aspect, altitude, lithology, land use, distance from streams, distance from roads, distance from faults, topographic wetness index, stream power index, stream transport index and plan curvature. For validation of the produced landslide susceptibility maps, the results of the analyses were compared with the field-verified landslide locations. Additionally, the receiver operating characteristic curves for all the landslide susceptibility models were constructed and the areas under the curves were calculated. The landslide locations were used to validate results of the landslide susceptibility maps. The verification results showed that the weights-of-evidence model (79.87%) performed better than certainty factor (72.02%) model with a standard error of 0.0663 and 0.0756, respectively. According to the results of the area under curve evaluation, the map produced by weights-of-evidence exhibits satisfactory properties.  相似文献   

The measurement of gamma-emitting radionuclides in beach sand cores of coastal regions of Ramsar,Iran using HPGe detectors     

Marziyeh Tari  Sayyed Ali Moussavi Zarandi  Kheirollah Mohammadi  Mohammad Reza Zare 《Marine pollution bulletin》2013

Radionuclides which present in different beach sands are sources of external exposure that contribute to the total radiation exposure of human. ²²⁶Ra, ²³⁵U, ²³²Th, ⁴⁰K and ¹³⁷Cs analysis has been carried out in sand samples collected at six depth levels, from eight locations of the northern coast of Iran, Ramsar, using high-resolution gamma-ray spectroscopy. The average Specific activities of natural radionuclides viz., ²²⁶Ra, ²³⁵U, ²³²Th, ⁴⁰K and ¹³⁷Cs, in the 0–36 cm depth sand were found as: 19.2 ± 0.04, 2.67 ± 0.17, 17.9 ± 0.06, 337.5 ± 0.61 and 3.35 ± 0.12 Bq kg⁻¹, respectively. The effects of organic matter content and pH value of sand samples on the natural radionuclide levels were also investigated. Finally, the measured radionuclide concentrations in the Ramsar beach were compared with the world average values, as reported by UNSCEAR (2000). None of the studied beaches were considered as a radiological risk.  相似文献   

New constraints on lithospheric thickness of the Iranian plateau using converted waves     

Najmieh Mohammadi  Forough Sodoudi  Elham Mohammadi  Ahmad Sadidkhouy 《Journal of Seismology》2013,17(3):883-895

The study of mantle lithosphere plays a key role to reveal predominant tectonic setting process of a region. The current geological and tectonic setting of Iran is due to the ongoing continental–continental collision of the Arabian and Eurasian plates. We applied a combined P and S receiver function analysis to the teleseismic data of nine permanent broadband seismic stations of the International Institute of Earthquake Engineering and Seismology located in different tectonic zones of Iranian plateau. More than 4 years of data were used to estimate the thickness of the crust and mantle lithosphere. According to our results, the crust is 50 km thick beneath the Zagros fold and thrust belt (ZFTB). We found the maximum Moho depth of approximately 70 km under the Sanandaj-Sirjan zone (SSZ) indicating the overthrusting of the crust of Central Iran onto the Zagros crust along the main Zagros thrust (MZT). Below the northeasternmost part of the Urumieh–Dokhtar Magmatic Arc (UDMA) and Central Iran, the Moho becomes shallower and lies at 40 km depth. Towards northeast, beneath the Alborz zone, the crust is 55 km thick. Based on S receiver functions, we provided new insights into the thickness of the Arabian and Eurasian lithospheres. The location of the boundary between these plates was estimated to be beneath the SSZ, which is slightly shifted northeastward relative to the surficial expression of the MZT. Furthermore, the Arabian plate is characterized by the relatively thick lithosphere of about 130 km beneath the ZFTB reaching 150 km beneath the SSZ, where the thickest crust was also observed. This may imply that the shortening across the Zagros is accommodated by lithospheric thickening. In contrast, UDMA and Central Iran are recognized by the thin lithosphere of about 80–85 km. This thin lithosphere may be associated with the asthenospheric upwelling caused by either lithospheric delamination or Neo-Tethys slab detachment beneath the Zagros collision zone.  相似文献